Chain extender imhando yezvinyorwa zvinogona kuwedzera ma molecular cheni uye kuwedzera iyo
molecular huremu nekuita neboka rinoshanda pane linear polymer cheni.
Inowanzo shandiswa kuvandudza ma mechanical properties uye kugadzirisa zvivakwa zve
polyurethane, polyester, naironi uye zvimwe zvigadzirwa.
Epoxy chain extender iketani inowedzera ine glycidyl methacrylate (GMA) .
Inowanzoshandiswa epoxy chain extenders inosanganisira styrene-glycidyl methacrylate, iyo ine
kugadzikana kwakanaka kwekupisa uye kunogona kupinda mhete-inovhura kemikari inopindirana nePA6, kwete
kusanganisa kwakachena kwemuviri.Inogona zvakare kushandiswa mumarara PET kudzokorodza uye zvimwe zvinhu.The
basa re epoxy chain extenders munylon yakagadziridzwa rakaita seinotevera:
1. Mhedzisiro pauremu hwemamorekuru uye intrinsic viscosity
Epoxy chain extenders inogona kuita neyekupedzisira amino boka uye yekupedzisira carboxyl boka re
PA6, uye wobva wavandudza huremu hwema molecular PA6.Zvisinei, gelation inogona kuitika panguva
iyo ketani yekuwedzera maitiro, saka zvinodikanwa kudzora akakodzera mamiriro, kunyanya
tembiricha uye screw kumhanya, kudzivirira kuyambuka-kubatanidza mune reactive extrusion.
Iyo intrinsic viscosity yePA6 yakawedzera nekukurumidza nekuwedzera kwehuwandu hweketani
extender.Kana zvirimo zveketani extender zvakawedzera kune imwe misa chikamu, iyo
intrinsic viscosity yePA6 yakadzikira zvishoma.Izvi zvinodaro nekuti iyo terminal boka rePA6 rinogona
ita nekukurumidza neboka re epoxy mucheni extender nekuda kwe polarity uye hydrogen
bond.Kana huwandu hweketani extender iri pakati nepakati, chikamu checheni refu
mamorekuru ari muhurongwa anowedzera uye viscosity inowedzera zvinoenderana;
Zvisinei, sezvomhinduro inoenderera, iyo yekupedzisira yeboka yePA6 inodzikira, uye kudhumhana
probability atkuguma kwema molecular cheni kunoderedzwa zvakanyanya nekuda kwesimba re
thermal diffusionuye kureba kwecheni ye molecular, kuwedzera, yakawandisa cheni extender
zvinogona kutungamirira kune adiki gel muhurongwa, izvo zvinotungamirira kuderera kwekuwedzera kweketani
kunyatsoshandauye PA6 intrinsic viscosity.
2. Mhedzisiro pamichina zvinhu
Iyo yakaenzana molecular mass yePA6 yakawedzerwa mushure mekuwedzera kweketani ne epoxy chain
extender, Kuoma kwezvinhu kunogona kuvandudzwa nekudzikira
crystallinity uye saizi yezviyo. Pamusoro pekuwedzera, nekuwedzera kwehurefu hwecheni yemamorekuru,
kusungirirwa pakati pemaketani kunowedzera, uye cheni ye molecular inonetsa kutsvedza.In
nenzira iyi, simba rekuita rinogona kutorwa nekuchinja kugadzirisa kwema molecular
cheni kana ichikanganiswa nenyika yekunze.Asi kana iyo misa chikamu chetani extender
inodarika imwe chikamu, zvese zvemakanika zvinhu zvinodzikiswa./n
3. Mhedzisiro pane rheological properties
Iyo melt flow rate (MFR) yakadzikira zvakanyanya nekuwedzera kwe epoxy chain extender,
zvichiratidza kuti epoxy chain extender uye PA6 yaive neanoshanda cheni yekuwedzera maitiro.
Nekuwedzera kwehuwandu hweketani extender, iyo equilibrium torque yakawedzera kekutanga
ndokuzodzikira, nekuti huremu hwemamorekuru hwePA6 mushure mekuwedzera ketani
yakawedzera, iyo inosungirirwa mucheni ye molecular yakawedzera, uye iyo yakanyunguduka viscosity zvakare
yakawedzera, nokudaro torque yekuenzanisa yakawedzera.
Nekufamba kwenguva, iyo PA6 pellet yakapfava, yakaumbwa uye yakanyungudutswa zvishoma nezvishoma, iyo
kushorwa kwe rotor kwakadzikira, uye torque zvakare yakaderera.
Qingdao Sainuo Chemical Co., Ltd.Isu tiri vagadziri vePE wakisi, PP wakisi,
OPEwax,EVAwax, PEMA, EBS,Zinc/Calcium Stearate….Zvigadzirwa zvedu zvapfuura
iyo REACH, ROHS, PAHS, FDA yekuongorora.
Sainuo zorora wakavimbiswa wakisi, gamuchira kubvunza kwako!
Webhusaiti: https://www.sanowax.com
E-mail:sales@qdsainuo.com
sales1@qdsainuo.com
Kero: Kamuri 2702,Block B, Suning Building, Jingkou Road, Licang District, Qingdao,
China
Nguva yekutumira: Kubvumbi-15-2021